EM Quant® Molybdenum Test,Catalog No. 10049
Test strips and reagent for the detection
and semi-quantitative determination of Molybdenum ions
General
The Molybdenum Test is chiefly used in the
analysis of boiler water and cooling water as a means of measuring
levels of molybdenum or molybdate added to inhibit corrosion. These
test strips allow a rapid semi-quantitative determination of most
inhibitors to be carried out outside the laboratory, to check that the
concentration is within the specified range. Please see the
manufacturer's instructions for the inhibitor concerned.
The test can also be used to determine
molybdenum on metallic surfaces, e.g. in order to differentiate
between stainless steels with and without molybdenum (V 4A and V 2A,
respectively).
Principle of the Method
Molybdenum reacts with toluene-3,4-dithiol in an
acidic solution to form a green color complex.
Graduation
0 - 5 - 20 - 50 - 100 - 250mg/l (ppm) Mo6+
Directions
- Rinse the measuring vessel several times
with some of the water sample and fill to the 5 ml mark.
- Add one microscoop of reagent and dissolve
by swirling.
- Immerse the reaction zone in the solution
for 1 minute.
- Remove the test strip, stroke the edge
against the rim of the vessel to remove excess liquid, and compare
the reaction zone with the color scale.
Note
For this test, the pH must be adjusted to below
pH 1. This value is normally reached by adding the reagent. If the
amount of reagent specified in the directions is not sufficient to
lower the pH to this value, adjust by adding more reagent, or
alternatively, adjust to pH 4-6 with 25% sulfuric acid prior to the
determination.
1mg/l MO5+ ~ 1.67mg/l MoO42+
Determination on Metallic Surfaces
Apply one drop of 25% hydrochloric acid and one
drop of 30% Perhydrol to the surface and stir to mix. When gas
development has ceased, add a spatula-tip of ascorbic acid and stir
until the yellow solution becomes colorless. Then apply 4 drops of
water, stir, hold the test strip against the surface for approximately
15 seconds, wait 1 minute and evaluate the reaction zone.
V 2A stainless steel reacts negatively.
V 4A stainless steel reacts positively.
There is a slightly different approach for
steels containing nickel.
Influence of Anions
The detection is not disturbed by less than:
| 1000mg/l |
Br, Cl,
CN, ClO3, ClO4,
CN, CO32, F,
I, NO2, NO3.
MnO4, OCN, PO43,
SCN, SO32, S2O32,
S2O42, S2O52,
S2O82 , WO42
, acetate, ascorbate, citrate, oxalate or tartrate. |
| 500mg/l |
BrO2 |
| 100mg/l |
CrO42, Cr2O72,
IO3, SeO32 |
| 10mg/l |
S2 |
Influence of Cations
The detection is not disturbed by less than:
| 1000mg/l |
Al3+, As3+, Ba2+,
Be2+, Ca2+, Cd2+, Cr3+,
Co2+, Fe2+, Fe3+, K+,
Li+, Mg2+, Mn2+, NH3+,
Na+, Ni2+, Pb2+, Rb+,
Sb3+, Sr2+, U6+, V4+,
Zn2+ |
| 100mg/l |
Ag+, Ce3+, Hg2+, Ti4+,
Zr4+ |
| 10mg/l |
Bi3+, Cu2+, Sn2+,
T+ |
Standard (1000mg/l)
Molybdenum standard solution, 500ml.
Package Size
10049 EM Quant® Test strips and
reagents
Molybdenum Test for 100 determinations
Purchase Molybdenum Test Strips 5-250 ppm EM Quant (1 PK of 100) HAZMAT fee incl
Gallade Part#: 10049-1
Mfr Part#: 10049-1
Brand: EMD Chemicals EM Science
Container: 1 PK of 100 Strips
Merck Index: 13.9006
Misc: HAZMAT UN2967 PGIII CORROSIVE
CAS Number: 5329-14-6
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