EM Quant® Manganese Test, Catalog No. 10080
Test strips and reagent for the detection
and semi-quantitative determination of manganese(II) ions
General
The Manganese Test can be used for routine
testing of ground water, industrial water and effluent. Another useful
application is the determination of potassium permanganate (KMnO4)
in boiler feed water.
It can also be used for quality control purposes
wherever manganese compounds are used in the manufacture of pigments,
paints and anti-corrosives, in tanneries, and within the textile
industry.
Principle of the Method
The determination is based on a redox reaction.
Following immersion in the sample solution, treatment of the reaction
zone with sodium hydroxide solution produces manganese dioxide, which
converts an organic redox indicator to a blue oxidation product in the
presence of acetic acid.
Graduation
0 - 5 - 25 - 100 - 500mg/l (ppm) Mn2+
Directions
- Immerse the test strip in the sample
solution for 1 second so that the reaction zone is thoroughly
moistened.
- Immerse the reaction zone for 15 seconds in 1mol/l solution sodium
hydroxide. . .
- . . .then for 45 seconds in 10% acetic acid.
- Remove the test strip, stroke the edge
against the rim of the vessel to remove excess liquid, and compare
the reaction zone with the color scale.
Notes
The pH of the sample solution should be between
1 and 7. Alkaline solutions must be buffered with sulfuric acid.
Because the Manganese Test contains a redox
indicator, it also responds to oxidizing cations and anions. The
presence of these ions is signalled, however, by a brown or blue
discoloration of the reaction zone on immersion in the sample
solution.
Other Reagents Required
1 mol/l sodium hydroxide solution and 96% acetic acid.
Influence of Anions
There is no interference at less than:
| 1000mg/l |
Br–, BrO3–,
Cl–, ClO3–, ClO4–,
CN–, F–, [Fe(CN)6]4–,
I–, IO3–, Mo7O246–,
N3-, NO3–, OCN–,
PO43–, SCN–, SO32–,
SO42–, S2O32–,
S2O52–, SeO32–,
WO42– , acetate, ascorbate, oxalate
succinate or tartrate. |
| 500mg/l |
S2O43– |
Influence of Cations
There is no interference at less than:
| 1000mg/l |
Al3+, As3+, Ba2+,
Be2+, Bi3+, Ca2+, Cd2+,
Co2+, Cu2+ , Hg2+, K+,mg2+, NH4+, Na+, Ni2+,
Pb2+, Rb+, Sb3+, Sn2+,
Sr2+, Tl+, Zn2+, Zr4+ |
In the presence of more than 500mg/l Ti4+,
Fe3+; 100mg/l Fe2+ or Cr3+, the
Mn(II) concentrations indicated are less than actually present.
In the presence of more than 250mg/l Fe3+
there is also a green discoloration.
More than 1000mg/l Co2+, Cu2+;
500mg/l Ag+; 250mg/l VO2, Hg+ or
10mg/l Ce3+/4+ give a false positive reaction for
manganese(II) ions by producing a color change of green to blue.
More than 10mg/l Au3+colors the
reaction zone green to brown.
Elimination of Interference
Mn2+ is detected in the presence of
NO2+, IO4–, [Fe(CN)6]3–
and S2O42+ by evaporating with
concentrated sulfuric acid. NO2– is destroyed by
adding amidosulfuric acid.
One gram of Amberlite® IRA-400 anion
exchanger removes:
100mg CrO42– at pH
0-6
60mg [Fe(CN)6]3–
at pH 1-7
300mg IO4 at pH 2-3
180mg S2O82–
at pH0-7
80mg VO3– at pH
5-7 or Au2+ at pH <1.5
Ti4+ is masked by adding 1 small
spatula tip of KF to approximately 5ml of the acidic solution (pH
1-2).
Fe2+ is oxidized to Fe3+
by H2O2 at pH >1. At higher iron(III)
concentrations, sodium acetate is added to the acidic solution (pH
1-2) to bring the pH to 4-4.8. After brief boiling and filtering, the
filtrate is tested as described. Ag+ and Hg+
are removed by adding NaCl.
Cd3+/4+ is removed by boilling for
2-3 minutes with calcium fluoride, molybdenum blue by shaking for 2-3
minutes with a small amount of cadmium powder, and Cr3+ by
adding ZnO and heating until the mixture boils. This procedure must be
repeated until the solution is colorless. VO2+ is oxidized
with KCIO, (boil for 2-3 minutes) and the VO3+
formed is then removed.
Standard (1000mg/l)
Manganese standard solution, 500ml.
Package Size
10080 EM Quant® Test strips and
reagent
Manganese Test for 100 determinations
Purchase Manganese Test Strips 200-100 ppm EM Quant (1 PK of 100) HAZMAT fee incl
Gallade Part#: 10080
Mfr Part#: 10080-1
Brand: EMD Chemicals EM Science
Container: 1 PK of 100 Strips
Misc: HAZMAT UN1824 PGII CORROSIVE
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