Reflectoquant® Chromate Test, Catalog No. 16988/1
1. Method
In acidic solutions, chromate is reduced to
Cr(III) by reacting with diphenylcarbazide. The resultant
diphenylcarbazone reacts with Cr(III) to form a red-violet complex,
the concentration of which is determined reflectometrically.
2. Measuring Range and Number of Determinations
| Measuring Range1) |
Number of Determinations |
1.0 - 45.0mg/l CrO42–
0.45 - 20.2mg/l Cr |
50 |
1) for conversion factors see
section 8
for measurement of concentrations > 45.0mg/l
CrO42–see section 6
3. Applications
Sample Material:
Wastewater, especially from electroplating
factories, and from the pickling and tanning industries.
4. Influence of Foreign Substances
This was checked - in the case of interfering
ions up to concentrations of 1,000mg/l - in solutions containing 25mg and
0mg/l CrO42–. The concentrations
of foreign substances given in the table lie below the limit at which
the determination is interfered with:
Concentrations of Foreign Substances in mg/l
or %
| Ag+ |
1,000 |
| Al3+ |
1,000 |
| Ascorbate |
1 |
| BO33- |
1,000 |
| Ca2+ |
1,000 |
| Cd2+ |
1,000 |
| Citrate |
1,000 |
| CN- |
100 |
| CO32- |
1,000 |
| Fe2+ |
1 |
| Fe3+ |
100 |
| K+ |
1,000 |
|
| Mg2+ |
1,000 |
| Mn2+ |
1,000 |
| Ni2+ |
1,000 |
| NO2- |
100 |
| NO3+ |
1,000 |
| Oxalate |
1,000 |
| Pb2+ |
1,000 |
| PO43- |
1,000 |
| S2O32- |
1 |
| Tartrate |
1,000 |
| Zn2+ |
1,000 |
| |
|
|
| EDTA |
100 |
| Anionic Surfactants1) |
1,000 |
| Cationic Surfactants2) |
1,000 |
| Nonionic Surfactants3) |
1,000 |
| H2O2 |
1 |
| NaCl |
1% |
| Na2SO4 |
1% |
|
1) tested with Na-dodecyl sulfate
2) tested with N-cetylpyridinium
chloride
3) tested with polyvinylpyrrolidone
5. Reagents and Auxiliaries
Please Note the Warnings on Labels!
The analytic test strips are stable at least up to the date stated on
the pack when stored in the closed tube at +15 to +25°·C.
Package Contents:
Tube containing 50 analytical test strips Bar code strip 1 bottle
of reagent CrO4–1
Other Reagents:
EM Quant® Chromate Test, Cat.
No. 10012, measuring range 3-100mg/l CrO42–
Chromate standard solution ready for use, 1,000mg/l Cat No. 1.19780, Merck, KGaA, Darmstadt, Germany
6. Preparation
- Check whether the chromate content is within
the measuring range
- Use the EM Quant® Chromate
Test as a guide. Samples containing more than 45.0 mg/l CrO42–
must be diluted with distilled water.
7. Procedure
- Observe the instructions for the RQflex Reflectometer.
The following applies to the Chromate Test:
Measurement procedure A. Stored reaction
time: 30 sec.
- Rinse the test vessel several times with the
solution to be tested (15-30°C). Then fill to the 10-ml mark.
- Add 10 drops of reagent CrO4–1
and swirl.
- Remove 1 analytical test strip and immediately
reclose the tube.
- Press START button of the reflectometer and
at the same time immerse both reaction zones of the test
strip in the measurement solution for approx. 2 sec.
- Shake off excess liquid from the test strip
- As soon as the beeper sounds (5 sec. before
end of reaction time), insert the test strip all the way into the
strip adapter with the reaction zones facing the display.
- Read off the result from the display. The
result is automatically stored.
Notes:
- If the test strip is inserted into the
adapter after the reaction time has expired, renewed depression of
the START button may result in a false reading of the chromate
concentration.
- At the end of each workday, cleanse the
strip adapter thoroughly with water or ethanol.
8. Conversions
| Units Required = |
Units Given x |
Conversion Factor |
| mg/l Cr |
mg/l CrO42– |
0.448 |
| mg/l CrO42– |
mg/l Cr |
2.23 |
9. Method Control
To check analytical test strips, equipment and
procedure:
Dilute chromate standard solution to 10 mg/l CrO42–
and analyze as described in section 7.
Purchase Chromate Test Strips 1.0-45.0 ppm Reflectoquant 1 PK *Req RQflex 2 #16950-1 HAZMAT fee incl
Gallade Part#: 16988-1
Mfr Part#: 16988-1
Brand: EMD Chemicals EM Science
Container: 1 PK of 50 Strips
Misc: HAZMAT UN2796 PGII CORROSIVE
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